全文获取类型
收费全文 | 39040篇 |
免费 | 5690篇 |
国内免费 | 4433篇 |
专业分类
化学 | 27914篇 |
晶体学 | 515篇 |
力学 | 2174篇 |
综合类 | 336篇 |
数学 | 4752篇 |
物理学 | 13472篇 |
出版年
2023年 | 676篇 |
2022年 | 773篇 |
2021年 | 1162篇 |
2020年 | 1358篇 |
2019年 | 1384篇 |
2018年 | 1179篇 |
2017年 | 1099篇 |
2016年 | 1681篇 |
2015年 | 1667篇 |
2014年 | 1992篇 |
2013年 | 2673篇 |
2012年 | 3279篇 |
2011年 | 3495篇 |
2010年 | 2519篇 |
2009年 | 2431篇 |
2008年 | 2618篇 |
2007年 | 2358篇 |
2006年 | 2191篇 |
2005年 | 1928篇 |
2004年 | 1459篇 |
2003年 | 1200篇 |
2002年 | 1180篇 |
2001年 | 959篇 |
2000年 | 828篇 |
1999年 | 783篇 |
1998年 | 669篇 |
1997年 | 614篇 |
1996年 | 622篇 |
1995年 | 539篇 |
1994年 | 502篇 |
1993年 | 434篇 |
1992年 | 401篇 |
1991年 | 343篇 |
1990年 | 301篇 |
1989年 | 259篇 |
1988年 | 217篇 |
1987年 | 156篇 |
1986年 | 183篇 |
1985年 | 186篇 |
1984年 | 119篇 |
1983年 | 79篇 |
1982年 | 85篇 |
1981年 | 60篇 |
1980年 | 59篇 |
1979年 | 60篇 |
1978年 | 43篇 |
1976年 | 38篇 |
1975年 | 38篇 |
1974年 | 42篇 |
1973年 | 49篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
中药一枝黄花、黄连、天麻、蛇床子中8种微量元素的测定 总被引:13,自引:2,他引:13
采用原子吸收光谱仪对一枝黄花、黄连、天麻、蛇床子中Fe、Ca、Mg、Mn、Cr、Cu、Zn、Pb八种无机元素的含量进行了测定,为进一步研究其药理和用途提供基础。 相似文献
992.
Yong Zhu Jin-lian Hu Kwok-wing Yeung Hao-jun Fan Ye-qiu 《高分子科学》2006,(2):173-186
SMPU (shape memory polyurethane) non-ionomers and ionomers, synthesized with poly(c-caprolactone) (PCL), 4, 4'-diphenylmethane diisocyanate (MDI), 1,4-butanediol (BDO), dimethylolpropionic acid (DMPA) were measured with cyclic tensile test and strain recovery test. The relations between the structure and shape memory effect of these two series were studied with respect to the ionic group content and the effect of neutralization. The resulting data indicate that, with the introduction of asymmetrical extender, the stress at 100% elongation is decreased for PU non-ionomer and ionomer series, especially lowered sharply for non-ionomer series; the fixation ratio of ionomer series is not affected obviously by the ionic group content; the total recovery ratio of ionomer series is decreased greatly. After sufficient relaxation time for samples stretched beforehand, the switching temperature is raised slightly, whereas the recovery ratio measured with strain recovery test method is lowered with increased DMPA content. The characterization with FT-IR, DSC, DMA elucidated that, the ordered hard domain of the two series is disrupted with the introduction of DMPA which causes more hard segments to dissolve in soft phase; ionic groups on hard segment enhance the cohesion between hard segments especially at high ionic group content and significantly facilitate the phase separation compared with the corresponding non-ionomer at moderate ionic group content. 相似文献
993.
Speciation analysis of inorganic arsenic by microchip capillary electrophoresis coupled with hydride generation atomic fluorescence spectrometry 总被引:5,自引:0,他引:5
A novel method for speciation analysis of inorganic arsenic was developed by on-line hyphenating microchip capillary electrophoresis (chip-CE) with hydride generation atomic fluorescence spectrometry (HG-AFS). Baseline separation of As(III) and As(V) was achieved within 54 s by the chip-CE in a 90 mm long channel at 2500 V using a mixture of 25 mmol l(-1) H3BO3 and 0.4 mmol l(-1) CTAB (pH 8.9) as electrolyte buffer. The precisions (RSD, n=5) ranged from 1.9 to 1.4% for migration time, 2.1 to 2.7% for peak area, and 1.8 to 2.3% for peak height for the two arsenic species at 3.0 mg l(-1) (as As) level. The detection limits (3sigma) for As(III) and As(V) based on peak height measurement were 76 and 112 microg l(-1) (as As), respectively. The recoveries of the spikes (1 mg l(-1) (as As) of As(III) and As(V)) in four locally collected water samples ranged from 93.7 to 106%. 相似文献
994.
995.
LiCl—HOAc和LiCl—HOAc—H2O体系(25℃)相图 总被引:2,自引:0,他引:2
测定了LiCl-HOAc和LiCl-HOAc-H_2O体系25℃时的溶度,绘制了溶度图.在LiCl-HOAc体系的相图中有LiCl及LiCl·1/2HOAc2种固相,后者是固液异成分化合物,体系中未发现LiCl·5HOAc或LiCL·HOAc的生成.LiCl-HOAc-H_2O体系25℃时的相图中有3种固相,即LiCl·H_2O、LiCl和LiCl·(1/2)HOAc.相变LiCl·H_2O→LiCl→LiCl·(1/2)HOAc表明HOAc在该三元体系中具有盐溶、脱水和溶剂合3种作用.此结果提供了一种制备无水LiCl的新方法. 相似文献
996.
Laiyuan Chen Liwu Lin Qin Xin Pinliang Ying Mojie Cheng Zhusheng Xu Tao Zhang 《Reaction Kinetics and Catalysis Letters》1995,56(2):267-272
It has been observed by FT-IR spectroscopy that both kinds of Brönsted acid protons present in HZSM-5 zeolite may be involved in the adsorption of methane at low temperature (173 K) and exchange with CH4 or CD4 at high temperature (>500°C). The sites which can adsorb methane at low temperature are the active sites for methane conversion at high temperature. Over HZSM-5 zeolite, the activation of methane is suggested to occur via a heterolytic cleavage of C–H bond with the assistance of protons. 相似文献
997.
998.
999.
通过对双环戊二烯的选择性羰基化加成,高产率地合成了三环[5、2、1、02,6]癸-3烯-8,9-二羧酸二甲酯。得到了无色透明的片状晶体,产率为90%。 相似文献
1000.
W. Y. Choy S. C. F. Au-Yeung S. Y. Fan W. L. A. K. Chiu C. S. Cockram 《Analytical and bioanalytical chemistry》1998,361(5):500-503
Glucose in 5% D2O/95% H2O solution was successfully determined quantitatively by measurements of the 1H NMR peak height (intensity) of the single peaks at δ(1H) = 5.22 and 4.64 ppm corresponding to the α-D and the β-D-glucose spectrum, respectively. The single peaks were obtained from decoupling of the high field part of the AX spectrum of the α-D- or the β-D-glucose by incorporation of time shared homonuclear decoupling in the WATR-CPMG method (WATR-HDCPMG) without re-attenuation of the water peak. The method was applied to the determination of total glucose in blood plasma from human subjects undergoing oral glucose tolerance test (OGTT) in the teaching hospital. The results compared favorably with those obtained from the standard glucose oxidase method obtained in a hospital pathology laboratory. The accuracy of the results obtained using the WATR-HDCPMG method was within 3.5% of the glucose oxidation method. 相似文献